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    Why study granular mixing? The simple answer lies in its
undeniable industrial importance. A more subtle reason is that mixing
flows generate unique qualitative patterns that are easily visualized
and verified; because of this, mixing studies allow relatively modest
computational experiments to effectively probe complex flows and to
test the robustness of model theories. In particular, particle dynamics
simulations allow access to information which would be very difficult
or impossible to measure in a physical experiment such as,
instantaneous force distributions, three dimensional concentration and
velocity profiles, etc. This project ostensibly focuses on cohesive
mixing, yet insight into granulation and aggregate break-up processes --
with implications far beyond granular mixing -- will be gained.
 
Computer simulation of heap formation both with and without
cohesion. As expected, cohesive effects become important near Bo~1
(i.e., when the cohesive force between the particles is roughly equal
to the particle weight). The static angle increases markedly with Bo <
1 (i.e., cohesive force > particle weight), while the dynamic angle --
obtained in a rotated tumbler -- remains relatively flat (the angle
increases for Bo > 1 and decreases for Bo <
1).
    Many of the industries which deal with particulate
materials are in some way affected by cohesion; most notably the
pharmaceutical, metallurgical, and pigment industries. Cohesion between
particles arises from a variety of sources: van der Waals forces,
electrostatic forces, and liquid bridging (capillary forces), to name a
few. These interparticle forces become increasingly important as
particle size decreases and, as cohesion becomes important, substantial
departure from the behavior of free-flowing particulate systems becomes
evident. For the case of free-flowing powders, it is necessary to
attempt to restrict particle motion in order to minimize segregation or
de-mixing. In contrast, in cohesive systems, particles tend to
segregate into aggregates that must be broken apart to attain a quality
mixture. Despite this fundamental difference, some of the tools that
have proven effective for the study of cohesionless materials can still
be employed for cohesive systems -- specifically, particle dynamics
simulations. To that end, a cohesive-solid particle dynamics code is
being developed to study the change in stable heap angle as a function
of global Bond number (the ratio of particle weight to attractive
force) as well as the evolution of mixing in a rotated drum. Here, we
are concerned with moderately sized particles, ~1mm, and so we devote
our attention to the forces attributable to interstitial liquid -- the
dominant interaction effect at these length scales.

A comparison of mixing at different Bo numbers. At left is a
qualitative comparison, after 2 revolutions, of the mixing within a
drum at different Bo numbers. A quantitative measure, based on the
interfacial area As, is plotted as a function of revolutions at right.
Note that the mixing rate for Bo = 0.025 is faster.
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