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Selected Publications

"Consecutive Rh(I)-catalyzed Alder-ene/Diels�Alder/Diels�Alder reaction sequence affording rapid entry to polycyclic compounds" Brummond, K. M.; You, L. Tetrahedron, 2005, 61, 6180-6185.

"Microwave-Assisted Intramolecular [2 + 2] Allenic Cycloaddition Reaction for the Rapid Assembly of Bicyclo[4.2.0]octa-1,6-dienes and Bicyclo[5.2.0]nona-1,7-dienes" Brummond, K. M.; Chen, D.; Org. Lett. 2005; 7(16); 3473-3475.

"A Formal Total Synthesis of (-)-FR901483, Using a Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclization Approach" Brummond, K. M.; Hong S.-p; J. Org. Chem.; 2005, 70 (3); 907-916.

"Heterocyclic alpha-Alkylidene Cyclopentenones Obtained via a Pauson-Khand Reaction of Amino Acid Derived Allenynes. A Scope and Limitation Study Directed Towards the Preparation of a Tricyclic Pyrrole Library" Brummond, K. M.; Curran, D. P.; Mitasev, B.; Fischer, S.  J. Org. Chem.; 2005, 70(5); 1745-1753.

"Allenes and Transition Metals: A Diverging Approach to Heterocycles"  Brummond, K. M.; Mitasev, B.; Org. Lett.; (Communication); 2004; 6(13); 2245-2248.

"Rhodium(I)-Catalyzed Ene-Allene Carbocyclization Strategy for the Formation of Azepines and Oxepines" Brummond, K. M.; Chen, H.; Mitasev, B.; Casarez, A. D.; Org. Lett.; (Communication); 2004; 6 (13); 2161-2163.

"Unique Strategy for the Assembly of the Carbon Skeleton of Guanacastepene A Using an Allenic Pauson-Khand-Type Reaction," K.M. Brummond*; D. Gao, Organic Lett., 2003, 5, 3491

"A Rhodium(I)-Catalyzed Allenic Alder-ene Reaction for the Rapid and Stereoselective Assembly of Cross-Conjugated Trienes," K.M. Brummond; H. Chen; P. Sill, L. You, J. Am. Chem. Soc., 2002, 124, 15186

"Chiral Nonracemic a-Silylidene Cyclopentenones from Chiral Allenes Using an Intramolecular Allenic Pauson-Khand-Type Cycloaddition," K.M. Brummond*; A.D. Kerekes; H. Wan, J. Org. Chem., 2002, 67, 5156

"An Allenic Pauson-Khand Reaction: A Reversal in p-Bond Selectivity and the Formation of Seven-Membered Rings," K.M. Brummond*; H. Chen; K.D. Fisher; A.D. Kerekes; B. Rickards; P.C. Sill; S.J. Geib, Organic Lett., 2002, 4, 1931

"A Silicon-Tethered Allenic Pauson-Khand Reaction," K.M. Brummond*; P.C. Sill, B. Rickards, S.J. Geib, Tetrahedron Lett., 2002, 43, 3735

"A Tandem Cationic Aza-Cope Rearrangement-Mannich Cyclization Approach to the Core Structure of FR901483 Via a Bridgehead Iminium Ion," K.M. Brummond*, J.Lu, Org. Lett., 2001, 3, 1347

"A Rapid Synthesis of Hydroxymethylacylfulvene (HMAF) Using the Allenic Pauson-Khand Reaction. A Synthetic Approach to Either Enantiomer of the Illudane Structure," K.M. Brummond*; J. Lu, J. Am. Chem. Soc., 2000, 122, 4915

"Recent Advances of the Pauson-Khand Reaction and Related [2 + 2 + 1] Cycloadditions," J.L. Kent; K.M. Brummond, Tetrahedron, 2000, 56, 3263

"An Expeditious Synthesis of the Potent Antitumor Agent, (�)-Hydroxymethylacylfulvene Using an Allenic Pauson-Khand Type Cycloaddition," K.M. Brummond*; J. Lu, J. Am. Chem. Soc., 1999, 121, 5087

"A Solid-Phase Synthesis of BRL 49653," K.M. Brummond*; J. Lu, J. Org. Chem., 1999, 64, 1723

"An Allenic [2 + 2 + 1] Cycloaddition." K.M. Brummond in Advances in Cycloaddition Chemistry, Volume 6 , M. Harmata, Ed., JAI Press, 1999, p. 211.

� a-Chlorination of Ketones Using p-Toluenesulfonyl Chloride. "K. M. Brummond*; K.D. Gesenberg; Tetrahedron Lett.   1999, 40, 2231.

"Polymorphism in Myristoylpalmitoylphosphatidylcholine." S. Tristram-Nagle;  Y. Isaacson; Y. Lyatskaya; Y. Liu; K. Brummond; J. Katsaras; J. Nagle. Chem. Phys. Lipids1999, 100 , 101.

�An Intramolecular Allenic [2+2+1] Cycloaddition.   K.M. Brummond*;  J.L. Kent;  H. Wan J. Org. Chem. 1998 , 63, 6535.

�A New Preparation of Alkynes from Vinyl Triflates.�  K.M. Brummond*;  K.D. Gesenberg;   J.L.Kent;  A.D. Kerekes Tetrahedron Lett.1998, 39, 8613.

� The Allenic Pauson-Khand Cycloaddition.  Dependence in p -Bond Selectivity on Substrate  Structure. �  K.M. Brummond*;  H. Wan Tetrahedron Lett.1998, 39, 931.

� Strategy for the Preparation of Allenes from a,b- Unsaturated and Saturated Ketones via Enol  Phosphates ." K.M. Brummond*;  E.A. Dingess;  J.L. Kent  J. Org. Chem.1996, 61, 6096.

"A New Allenic Pauson-Khand Cycloaddition for the Preparation of a -Methylene  Cyclopentenones. "   J.L. Kent;  H. Wan;  K.M. Brummond* Tetrahedron Lett.1995 , 36, 2407.

"Facile Intramolecular Carbolithiation Reactions of Alkylthio- and Alkoxyacetylenes by  Stabilized Carbanions.  A Novel Strategy for the Synthesis of Functionalized Carbocycles."  R.L.  Funk;  G.L. Bolton;  K.M. Brummond;  K.E. Ellestad;  J.B. Stallman J. Am. Chem. Soc.1993,  115,7023.

"Stereoselective Preparation of Vinyl Sulfones by Protodesilylation of Allyl Silanes." R.L.  Funk;  J. Umstead-Daggett;  K.M. Brummond Tetrahedron Lett. 1993, 34, 2867.

"Generation of Ketenes from Carboxylic Acids Using the Mukaiyama Reagent (N-Methyl-2- chloropyridinium Iodide). "  R.L. Funk;  K.M. Brummond;  M.M. Abelman Syn. Lett.1989 , 1,36.