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Publications

[1]   Dutta, S., Ren, Z., Brinzer, T., and Garrett-Roe, S. “Two-dimensional ultrafast vibrational spectroscopy of azides in ionic liquids reveals solute-specific solvation”  Phys. Chem. Chem. Phys.  Article ASAP  (2015). doi:10.1039/C5CP02119G.

[2]   Ivanova, A. S., Brinzer, T., Roth, E. A., Kusuma, V. A., Watkins, J. D., Zhou, X., Luebke, D., Hopkinson, D., Washburn, N. R., Garrett-Roe, S., and Nulwala, H. B. “Eutectic ionic liquid mixtures and their effect on CO2 solubility and conductivity” RSC Adv. 5, 51407–51412 (2015). doi:10.1039/C5RA06561E.

[3]   Brinzer, T., Berquist, E. J., Ren, Z., Dutta, S., Johnson, C. A., Krisher, C. S., Lambrecht, D. S., and Garrett-Roe, S. “Ultrafast vibrational spectroscopy (2D-IR) of CO2 in ionic liquids: Carbon capture from carbon dioxide’s point of view” J. Chem. Phys. 142, 212425 (2015). doi:10.1063/1.4917467.

[4]   Ren, Z., Brinzer, T., Dutta, S., and Garrett-Roe, S. “Thiocyanate as a local probe of ultrafast structure and dynamics in imidazolium-based ionic liquids: Water induced heterogeneity and cation induced ion-pairing” J. Phys. Chem. B 119, 4699–4712 (2015). doi:10.1021/jp512851v.

[5]   Cui, X., Wang, C., Argondizzo, A., Garrett-Roe, S., Gumhalter, B., and Petek, H. “Transient excitons at metal surfaces” Nature Physics 10, 505–509 (2014). doi:10.1038/nphys2981.

[6]   Ren, Z., Ivanova, A. S., Couchot-Vore, D., and Garrett-Roe, S. “Ultrafast structure and dynamics in ionic liquids: 2D-IR spectroscopy probes the molecular origin of viscosity” J. Phys. Chem. Lett. 5, 1541–1546 (2014). doi:10.1021/jz500372f.

[7]   Borek, J., Perakis, F., Kläsi, F., Garrett-Roe, S., and Hamm, P. “Azide–water intermolecular coupling measured by 2-color 2D-IR spectroscopy” J. Chem. Phys. 136, 224503 (2012). doi:10.1063/1.4726407.

[8]   Bloem, R., Garrett-Roe, S., Strzalka, H., Hamm, P., and Donaldson, P. “Enhancing signal detection and completely eliminating scattering using quasi-phase-cycling in 2D IR experiments”  Opt. Express 18, 27067 (2010). doi:10.1364/OE.18.027067.

[9]   Garrett-Roe, S., Perakis, F., Rao, F., and Hamm, P. “3D-IR spectroscopy of isotopically substituted liquid water reveals heterogeneous dynamics” J. Phys. Chem. B 115, 6976–6984 (2011). doi:10.1021/jp201989s.

[10]   Rao, F., Garrett-Roe, S., and Hamm, P. “Structural inhomogeneity of water by complex network analysis” J. Phys. Chem. B 114, 15598–15604 (2010). doi:10.1021/jp1060792.

[11]   Garrett-Roe, S. and Hamm, P. “The OH stretch vibration of liquid water reveals hydrogen-bond clusters” Phys. Chem. Chem. Phys. 12, 11263–11266 (2010). doi:10.1039/C004579A.

[12]   Garrett-Roe, S. and Hamm, P. “What can we learn from 3D-IR spectroscopy?”  Acc. Chem. Res.  42, 1412–1422 (2009). doi:10.1021/ar900028k.

[13]   Garrett-Roe, S. and Hamm, P. “Purely absorptive three-dimensional infrared spectroscopy (3D-IR)” J. Chem. Phys. 130, 164510 (2009). doi:10.1063/1.3122982.

[14]   Backus, E., Garrett-Roe, S., and Hamm, P. “On the phasing problem of heterodyne-detected two-dimensional infrared spectroscopy” Opt. Lett. 33, 2665–2667 (2008). doi:10.1364/OL.33.002665.

[15]   Strader, M. L., Garrett-Roe, S., Szymanski, P., Shipman, S. T., Johns, J. E., Yang, A., Muller, E., and Harris, C. B. “The ultrafast dynamics of image potential state electrons at the dimethylsulfoxide/Ag(111) interface” J. Phys. Chem. C 112, 6880–6886 (2008). doi:10.1021/jp7116664.

[16]   Yang, A., Shipman, S. T., Garrett-Roe, S., Johns, J. E., Strader, M. L., Szymanski, P., Muller, E., and Harris, C. B. “Two-photon photo-emission of ultrathin film PTCDA morphologies on Ag(111)” J. Phys. Chem. C 112, 2506–2513 (2008). doi:10.1021/jp076632q.

[17]   Koziński, M., Garrett-Roe, S., and Hamm, P. “2D-IR spectroscopy of the sulfhydryl band of cysteines in the hydrophobic core of proteins” J. Phys. Chem. B 112, 7645–7650 (2008). doi:10.1021/jp8005734.

[18]   Garrett-Roe, S. and Hamm, P. “Three-point frequency fluctuation correlation functions of the OH-stretch in liquid water” J. Chem. Phys. 128, 104507 (2008). doi:10.1063/1.2883660.

[19]   Koziński, M., Garrett-Roe, S., and Hamm, P. “Vibrational spectral diffusion of CN- in water” Chem. Phys. 341, 5–10 (2007). doi:10.1016/j.chemphys.2007.03.024.

[20]   Garrett-Roe, S. and Hamm, P. “Fifth-order non-linear spectroscopy to probe non-Gaussian stochastic processes” in Proceedings of the thirteenth international conference on time-resolved vibrational spectroscopy (2007).

[21]   Shipman, S. T., Garrett-Roe, S., Szymanski, P., Yang, A., Strader, M. L., and Harris, C. B. “Determination of band curvatures by angle-resolved two-photon photoemission in thin films of C60 on Ag(111)” J. Phys. Chem. B 110, 10002–10010 (2006). doi:10.1021/jp055042u.

[22]   Garrett-Roe, S., Shipman, S. T., Szymanski, P., Strader, M. L., Yang, A., and Harris, C. B. “Ultrafast electron dynamics at metal interfaces: Intraband relaxation of image state electrons as friction” J. Phys. Chem. B 109, 20370–20378 (2005). doi:10.1021/jp051977z.

[23]   Szymanski, P., Garrett-Roe, S., and Harris, C. B. “Time- and angle-resolved two-photon photoemission studies of electron localization and solvation at interfaces”  Prog. Surf. Sci.  78, 1–39 (2005).doi:10.1016/j.progsurf.2004.08.001.

[24]   Bezel, I., Gaffney, K. J., Garrett-Roe, S., Liu, S. H., Miller, A. D., Szymanski, P., and Harris, C. B. “Measurement and dynamics of the spatial extent of the spatial distribution of an electron localized at a metal–dielectric interface” J. Chem. Phys. 120, 845–856 (2004).

[25]   Harris, C. B., Szymanski, P., Garrett-Roe, S., Miller, A. D., Gaffney, K. J., Liu, S. H., and Bezel, I. “Electron localization and solvation in two dimensions”  Proc. Soc. Photo-opt. Instrum. Eng. (SPIE) 5223, 159–168 (2003).

[26]   Bezel, I., Gaffney, K., Garrett-Roe, S., Liu, S. H., Miller, A. D., Szymanski, P., and Harris, C. B. “The size of a localized electron at a metal/adsorbate interface” in Springer series in chemical physics volume 71 pages 310–312 (2003).

[27]   Snee, P. T., Garrett-Roe, S., and Harris, C. B. “Dynamics of an excess electron at metal/polar interfaces” J. Phys. Chem. B 107, 13608 (2003). doi:10.1021/jp022665o.

[28]   Liu, S. H., Miller, A. D., Gaffney, K. J., Szymanski, P., Garrett-Roe, S., Bezel, I., and Harris, C. B. “Direct observation of two-dimensional electron solvation at alcohol/Ag(111) interfaces” J. Phys. Chem. B 106, 12908–12915 (2002). doi:10.1021/jp025772r.

[29]   Miller, A. D., Gaffney, K. J., Liu, S. H., Szymanski, P., Garrett-Roe, S., Wong, C. M., and Harris, C. B. “Evolution of a two-dimensional band structure at a self-assembling interface” J. Phys. Chem. A 106, 7636–7638 (2002).

[30]   Miller, A. D., Bezel, I., Gaffney, K. J., Garrett-Roe, S., Liu, S. H., Szymanski, P., and Harris, C. B. “Electron solvation in two dimensions” Science 297, 1163–1166 (2002). doi:10.1126/science.1073571.

[31]   Garrett-Roe, S. and Warren, W. S. “Numerical studies of intermolecular multiple quantum coherences: High-resolution NMR in inhomogeneous fields and contrast enhancement in MRI” J. Magn. Reson. 146, 1–13 (2000). doi:10.1006/jmre.2000.2096.

[32]   Rizi, R. R., Ahn, S., Alsop, D. C., Garrett-Roe, S., Mescher, M., Richter, W., Schnall, M. D., Leigh, J. S., and Warren, W. S. “Intermolecular zero-quantum coherence imaging of the human brain” Magn. Reson. Med. 43, 627–632 (2000).

Covers

The hydrogen-bond-network network of water displays multiple free-energy basins.

Charge transport: orbital symmetries dictate the carrier dispersion.

Friction on the femtosecond time scale: the cooling of photoexcited interfacial electrons.

Quantum/classical calculations of an excess electron at a methanol/platinum surface.

Two-dimensional electron solvation dynamics observed by two-photon photoemission at alcohol/Ag(111) interfaces.