77) Afeke, C; Xie, Y; Floreancig, P. E. "Re2O7-catalyzed Approach to Spirocyclic Ether Formation from Acyclic Precursors: Observation of Remote Stereoinduction" Org. Lett. 2019, 21, 5064-5067. DOI:10.1021/acs.orglett.9b01660 link

Vertical Divider

76) Caplan, S. M.; Floreancig, P. E. "Total Synthesis of Divergolides E and H" Angew. Chem. Int. Ed. 2018, 57, 15866-15870. DOI: 10.1002/angie.201810336 link

Vertical Divider

75) Hanna, R. D.; Naro, Y.; Deiters, A.; Floreancig, P. E. "Potent and Readily Accessible Bistramide A Analogues through Diverted Total Synthesis" Chem. Eur. J. 2018, 24, 16271-16275. DOI: 10.1002/chem.201804417 link

Vertical Divider

74) Qin, Q.; Xie, Y.; Floreancig, P. E. "Diarylmethane synthesis through Re2O7-catalyzed bimolecular dehydrative Friedel-Crafts reactions" Chem. Sci. 2018, 9, 8528-8534. DOI: 10.1039/c8sc03570a link
Highlighted in Synform Link

Vertical Divider

73) Yang, F.; Li, Y.; Floreancig, P. E.; Li, X.; Liu, L. "Copper-catalyzed oxidative cross-dehydrogenative coupling of 2H-chromenes and terminal alkynes" Org. Biomol. Chem. 2018, 16, 5144-5149. DOI: 10.1039/c8ob00949j link

Vertical Divider

72) Morales-Rivera, C. A.; Floreancig, P. E.; Liu, P. "Predictive Model for Oxidative C-H Bond Functionalization Reactivity with 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone" J. Am. Chem. Soc. 2017, 139, 17935-17944. DOI: 10.1021/jacs.7b08902 link

Vertical Divider

71) Rohrs, T. M.; Qin, Q.; Floreancig, P. E. "Re2O7-Mediated Dehydrative Cyclization Reactions: Total Synthesis of Herboxidiene and Its 12-Desmethyl Analogue" Angew. Chem. Int. Ed. 2017, 56, 10900-10904. DOI: 10.1002/angie.201705924 link

Vertical Divider

70) Hanna, R. D.; Naro, Y.; Deiters, A.; Floreancig, P. E. "Alcohol, Aldehyde, and Ketone Liberation and Intracellular Cargo Release through Peroxide-​Mediated α-​Boryl Ether Fragmentation" J. Am. Chem. Soc. 2016, 138, 13353-13360. DOI:10.1021/jacs.6b07890 link

Vertical Divider

69) Peh, G. R.; Floreancig, P. E. “Convergent One-Pot Oxidative [n+1] Approaches to Spiroacetal Synthesis” Org. Lett. 2015, 17, 3750-3753. DOI:10.1021/acs.orglett.5b01736 link

Vertical Divider

68) Sun, S.; Li, C.; Floreancig, P. E.; Lou, H; Liu, L. “Highly Enantioselective Catalytic Cross-Dehydrogenative Coupling of N-Carbamoyl Tetrahydroisoquinolines and Terminal Alkynes” Org. Lett. 2015, 17, 1684-1687. DOI: 10.1021/acs.orglett.5b00447. link
Highlighted in Synfacts. link

Vertical Divider

67) Floreancig, P. E. “Structure Inspires a New Method that Delivers the Synthesis of Natural Products and Analogs in the Pederin Family” in Strategies and Tactics in Organic Synthesis Harmata, M., Ed. 2014, 10, 183-205.

66) Han, X.; Floreancig, P. E. “Spiroacetal Formation through Telescoped Cycloaddition and Carbon–Hydrogen Bond Functionalization: Total Synthesis of Bistramide A” Angew. Chem., Int. Ed. 2014, 53, 11075. DOI: 10.1002/anie.201406819. link

Vertical Divider

65) Xie, Y.; Floreancig, P. E. “Heterocycle Synthesis Based on Allylic Alcohol Transposition Using Traceless Trapping Groups” Angew. Chem., Int. Ed. 2014, 53, 4926-4929. DOI: 10.1002/anie.201402010. link
Highlighted in Synfacts. link

Vertical Divider

64) Lu, C.; Floreancig, P. E. “Stereocontrolled Cyanohydrin Ether Synthesis through Chiral Bronsted Acid-Mediated Vinyl Ether Hydrocyanation” J. Org. Chem. 2013, 78, 9366-9376. DOI: 10.1021/jo4016002. link

Vertical Divider

63) LaPorte, M.; Tsegay, S.; Hong, K. B.; Lu, C.; Fang, C.; Wang, L.; Xie, X.-q.; Floreancig, P. E. “Construction of a Spirooxindole Amide Library through Nitrile Hydrozirconation-Acylation-Cyclization Cascade” ACS Comb. Sci. 2013, 15, 344-349. DOI: 10.1021/co4000387. link
Selected for the cover. link

Vertical Divider

62) Cui, Y.; Villafane, L. A.; Clausen, D. J.; Floreancig, P. E. “Bimolecular Coupling Reactions through Oxidatively Generated Aromatic Cations: Scope and Stereocontrol” Tetrahedron 2013, 69, 7618-7626. DOI; 10.1016/j.tet.2013.05.011. Invited article for an issue in honor of Paul Wender receiving the Tetrahedron Award. link

Vertical Divider

61) Han, X.; Peh, G. R.; Floreancig, P. E. “Prins-Type Cyclization Reactions in Natural Product Synthesis” Eur. J. Org. Chem. 2013, 1193-1208. link

60) Xie, Y.; Floreancig, P. E. “Cascade Approach to Stereoselective Polyether Formation: Epoxides as Trapping Agents for Transposing Allylic Alcohols” Angew. Chem., Int. Ed. 2013, 52, 625-628. link

Vertical Divider

59) Wu, C.-Y.; Feng, Y.; Cardenas, E. R.; Williams, N.; Floreancig, P. E.; De Brabander, J. K.; Roth, M. G. “Studies toward the Unique Pederin Family Member Psymberin: Structure–Activity Relationships, Biochemical Studies, and Genetics Identify the Mode-of-Action of Psymberin” J. Am. Chem. Soc. 2012, 134, 18998-19003. link

Vertical Divider

58) Peh, G. R.; Floreancig, P. E. “Cyclopropane Compatibility with Oxidative Carbocation Formation: Total Synthesis of Clavosolide A” Org. Lett. 2012, 14, 5614-5617. link

Vertical Divider

57) Han, X.; Floreancig, P. E. “Synthesis of Bridged Inside-Outside Bicyclic Ethers through Oxidative Transannular Cyclization Reactions” Org. Lett. 2012, 14, 3808-3811. link

Vertical Divider

56) Clausen, D. J.; Floreancig, P. E. “Aromatic Cations from Oxidative Carbon–Hydrogen Bond Cleavage in Bimolecular Carbon–Carbon Bond Forming Reactions” J. Org. Chem. 2012, 77, 6574-6582. link
Highlighted in Organic Process and Research Development. link

Vertical Divider

55) Mosey, R. A.; Floreancig, P. E. “Isolation, Biological Activity, Synthesis, and Medicinal Chemistry of the Pederin/Mycalamide Family of Natural Products” Nat. Prod. Rep. 2012, 29, 980-995. link

54) Mosey, R. A.; Floreancig, P. E. “Versatile Approach to alpha-Alkoxy Carbamate Synthesis and Stimulus-Responsive Alcohol Release” Org. Biomol. Chem. 2012, 10, 7980-7985. link

Vertical Divider

53) Minami, S. S.; Sun, B.; Popat, K.; Kauppinen, T.; Pleiss, M.; Zhou, Y.; Ward, M. E.; Floreancig, P.; Mucke, L.; Desai, T.; Gan, L. “Selective Targeting of Microglia by Quantum Dots” J. Neuroinflam. 2012, 9, 22. link

52) Cui, Y.; Floreancig, P. E. “Synthesis of Sulfur-Containing Heterocycles through Oxidative Carbon–Hydrogen Bond Functionalization” Org. Lett. 2012, 14, 1720-1723. link
Highlighted in Synfacts. link

Vertical Divider

51) Brizgys, G. J.; Jung, H. H.; Floreancig, P. E. “Stereoselective Piperidine Synthesis through Oxidative Carbon–Hydrogen Bond Functionalizations of Enamides” Chem. Sci. 2012, 3, 438-442. link
One of the ten most accessed articles in October, 2011 for Chemical Science.

Vertical Divider

50) Cui, Y.; Balachandran, R.; Day, B. W.; Floreancig, P. E. “Synthesis and Biological Evaluation of Neopeltolide and Analogs” J. Org. Chem. 2012, 77, 2225-2235. link

Vertical Divider

49) Wan, S.; Wu, F.; Rech, J. C.; Green, M. E.; Balachandran, R.; Horne, W. S.; Day, B. W.; Floreancig, P. E. “Total Synthesis and Biological Evaluation of Pederin, Psymberin, and Highly Potent Analogs” J. Am. Chem. Soc. 2011, 133, 16668-16679. link

Vertical Divider

48) Xie, Y.; Floreancig, P. E. “Stereoselective Heterocycle Synthesis through a Reversible Allylic Alcohol Transposition and Nucleophilic Addition Sequence” Chem. Sci. 2011, 2, 2423-2427. link

Vertical Divider

47) Zaware, N.; LaPorte, M. G.; Farid, R.; Liu, L.; Wipf, P.; Floreancig, P. E. “Diversity-Oriented Synthesis of a Library of Substituted Tetrahydropyrones using Oxidative Carbon–Hydrogen Bond Activation and Click Chemistry” Molecules 2011, 16, 3648-3662. link 

46) Clausen, D. J.; Wan, S.; Floreancig, P. E. “Total Synthesis of the Protein Phosphatase 2A Inhibitor Lactodehydrothyrsiferol” Angew. Chem., Int. Ed. 2011, 50, 5178-5181. link
Highlighted in Synfacts. link

Vertical Divider

45) Wu, F.; Green, M. E.; Floreancig, P. E. “Total Synthesis of Pederin and Analogs”  Angew. Chem., Int. Ed. 2011, 50, 1131-1134. link

Vertical Divider